ENHANCED PHOTOCATALYTIC DEGRADATION EFFICIENCY OF GREEN OXIDANT COMBINED STRONTIUM AND NITROGEN-CODOPED TiO2 OVER REACTIVE ORANGE 30 UNDER NATURAL SUN LIGHT IRRADIATION Authors: Sivakumar M , RAVISHANKAR M* KRISHNAN E AND SIVAKUMAR S
ABSTRACT
The photocatalytic activity of Sr, N-codoped TiO2 photocatalysts was investigated by the
degradation of Reactive Black 5 (RB 5) under natural sunlight irradiation. A series of Sr, Ncodoped
TiO2 photocatalysts with different dopant concentrations (0.001 M%, 0.003 M %, 0.005
M %, 0.007 M %, and 0.009 M %) were synthesized by sol-gel route. Initially, photocatalytic
activity of the pure TiO2 was hindered due to its poor surface properties and low utilization of
visible light. To minimize these bottle neck drawbacks of TiO2 photocatalyst, the doping
treatment of Strontium and Nitrogen. The photocatalytic activity of Sr, N-codoped TiO2
photocatalysts was remarkably higher than that of the as-prepared sample. The highlighted
photocatalytic properties of Sr, N-codoped TiO2 were confirmed by X-ray powder diffraction
(XRD), Scanning electron microscopy (SEM), UV-visible diffused reflectance spectroscopy
(UV-DRS) and Photoluminescence spectra (PL). 0.007% Sr, N-codoped TiO2 has photostability
and long durability. Further, green oxidant (H2O2) combined photocatalytic activity process
carried out with highly reactive 0.007% Sr, N-codoped TiO2 photocatalyst.
Keywords: Sr, N-Codoped TiO2, sol-gel route, Photocatalytic Degradation, Reactive
Orange 30 and Natural Sun Light, green oxidant, semiconductor Publication date: 01/08/2020 https://ijbpas.com/pdf/2020/August/MS_IJBPAS_2020_5121.pdfDownload PDFhttps://doi.org/10.31032/IJBPAS/2020/9.8.5121