TRACE ELEMENTAL ANALYSIS OF HAIR FOR TOXICITY USING PARTIAL INDUCED X-RAY EMISSION (PIXE) TESTING FOR FORENSIC SCIENCE APPLICATIONS Authors: WAQAS M , SHAHZAD MS2, ALI A1*, MALIK A1, AHMAD I3, BUTT M1, HASSAN M4, ASHRAF W1, REHMAN M5
ABSTRACT
Background: Trace metals and elements are the vital component of the body but their excessive
amount can be the hallmark for survival. Workmanship of industries like pharmaceutical, paint,
and textile are more prone to accumulate them in their bodies and cause toxicity. Hair analysis of
workers could be useful for criminal investigations. PIXE is technique which plays vital role in
detection of elements and metals with fine accuracy to even less than 1 ppm (particles per
million) and provides all present metallic profiles simultaneously.
Method: PIXE is a novel technique used for identification of metals and advantageous over
other methods due to its efficacy on the range of metals, the amount of the sample and the
quickness. Samples of 31 people (related from three industries pharmaceutical, paint and textile)
including 5 normal were analyzed for detection of trace elements from hair.
Results: Trace metals (Se, Cr, Fe, Cu, Zn, and Ni) identified from workers of all three industries
pharmaceutical, paint and textile with varying concentrations and with observable difference
from control group (people not working in industry). Results are encouraging as it could have
vital applications in forensic science as hair from crime scene could lead to significant
information about the standard of living of person and ultimately to access him.
Conclusion: Outcome of present study will help us to detection the toxicity of trace metals in
workers expressing in terms of diseases and for identification purpose, it is a powerful marker in
criminal investigation.
Keywords: Forensic, metal, toxicity, hair, trace element